曹 松 教授 博士 (Prof. Dr. Song Cao)
电话：021-64253452传真：021-64252603
地址：ylzz总站线路检测实验十八楼1423室
E-mail: scao@ecust.edu.cn
个人简介
yl34511线路中心教授、博士生导师。分别在华东师范大学化学系、南京大学化学化工学院、ylzz总站线路检测化学与制yl34511线路中心获得学士、硕士、博士学位。2000年起在ylzz总站线路检测化学与制yl34511线路中心从事科研与教学工作。2006.4–2007.4以访问学者身份赴美国西北大学化学系从事帕金森药物的设计与合成。2013.7–2013.10以高级访问学者身份赴英国南安普顿大学化学系从事药物的设计与合成。
作为项目负责人承担了上海科委科技创新和攻关项目；负责国家自然科学基金面上项目三项：“合成含二氟甲基(CF2)的结构多样性小分子的新策略”、“过渡金属催化的多氟芳烃的碳氟键的活化：碳氢化及官能团化”以及“基于碳氟键和碳氢键活化的碳碳偶联反应”；负责十二五科技支撑计划一项；作为课题组副组长负责国家863一项课题(第一、滚动、加强)以及国家973的子课题一项。
以主要作者在国际核心学术期刊如Chem Commun、Org Lett、Chem. Eur. J.、Adv Synth Catal、ChemCatChem、J Org. Chem、Green Chem、Eur. J Org. Chem、Tetrahedron、Org Biomol Chem、Tetrahedron Lett、Synlett、J Agric and Food Chem、J Fluorine Chem等发表论文七十多篇；授权国家发明专利五项，公开中国发明专利10项、国际专利一项。现指导博士和硕士研究生多名。
2018年10月起担任国际学术期刊J Fluorine Chem的编委会成员(Editorial Board)。
Tetrahedron、Tetrahedron Letters、Org Biomol Chem、Chem Comm、J Org. Chem、Org Chem Front,、J Fluorine Chem、J Agric Food Chem、Org Lett、Adv Synth Catal及化学学报、有机化学、中国化学等期刊的审稿人。
研究方向
1.碳氟键的活化及官能团化；新型含氟砌块的多组分反应；含氟活性化合物的合成。
2.作用靶标特异的仿生农药化学：昆虫生长调节剂(苯甲酰脲类几丁质抑制剂、具有蜕皮激素活性的非甾醇类二芳酰肼类化合物)；含恶二唑哒嗪酮类化合物拒食剂；鱼尼丁受体氟虫双酰胺、氯虫苯甲酰胺类化合物。
3.高效有机合成方法学(新型多组分反应的设计；多组分反应在农药、医药中的应用；点击化学参与的多组分反应)。
欢迎报考农药点博士生和硕士研究生！
获奖成果
Ø“芳香杂环及含氟仿生农药的分子设计、合成制备及构效关系”获2003年度教育部自然科学一等奖(第二完成人)
Ø“含氟芳香精细化学品及氟化试剂的关键技术、理论与应用及产业化”获2008年度国家科技进步奖二等奖(第四完成人)
代表性论著
以下为近期以通讯作者发表的论文：
2019年
Facile synthesis of unsymmetrical 2,5-disubstituted 1,3,4-oxadiazoles by the cyclization of gem-difluoroalkenes with acyl hydrazides
Xuxue Zhang,* Jingjing He and Song Cao*
Asian J of Org Chem, 2019, 8, 279–282
镍催化的偕二氟芳基乙烯与有机锌交叉偶联反应立体选择性合成(Z)-单氟烯烃
张娟, 王碧云, 刘熠森, 曹松*
有机化学, 2019, 39, 249–256 (Invited)
Copper-catalyzed synthesis of gem-difluoroallylboronates from a-trifluoromethyl alkenes and B2pin2
Xianghu Zhao, Chunmei Li, Biyun Wang and Song Cao*
Tetrahedron Lett, 2019, 60, 129–132
2018年
基于碳氟键断裂的硼化反应
曹松
应用技术学报, 2018, 18 (4), 366–369 (Invited，亮点介绍)
以乙腈为氰基源合成4-氰基偕二氟芳基乙烯
刘青雲, 赵祥虎, 李佳录, 曹松*
化学学报, 2018, 76, 945–950 (Invited，封面)
Synthesis of difluoromethylated enynes by the reaction of α-(trifluoromethyl)styrenes with terminal alkynes
Mingsheng Wu, Xianghu Zhao, Yisen Liu, and Song Cao*
Org Biomol Chem, 2018, 16, 6909–6917
LiHMDS-promoted Palladium or Iron-Catalyzed ipso-Defluoroborylation of Fluoroarenes
Xianghu Zhao, Mingsheng Wu, Yisen Liu, and Song Cao*
Org Lett, 2018, 20(18), 5564−5568 (分别被公众号CGB资讯、有机合成路线分享、康龙化成、Synfacts报道)
A facile synthesis of 3-arylindenes by HMPA-promoted direct arylation of indenes with aryl fluorides
Xinfei Ji, Jialu Li, Mingsheng Wu, Song Cao*
ACS Omega, 2018, 3, 10099−10106 (Invited)
Direct C(sp3)−H difluoroallylation of diarylmethanes with a-(trifluoromethyl) styrenes at room temperature
Xinfei Ji, Yisen Liu, Hongyan Shi, Song Cao*
Tetrahedron, 2018, 74, 4511−4519 (Invited)
Fabrication of charge-conversion nanoparticles for cancer imaging by flash nanoprecipitation
Meng Li, Yisheng Xu*, Jinli Sun, Mingwei Wang, Dahai Yang, Xuhong Guo, Haiyun Song, Song Cao*, Yunfeng Yan*
ACS Appl. Mater. Interfaces, 2018, 10, 10752−10760 IF: 8.097 (合作论文)
Stereoselective Copper- or Nickel-Catalyzed Tertiary, Secondary, and Primary Alkylation of Monofluoroalkenes with Grignard Reagents
Hongyan Shi, Wenpeng Dai, Biyun Wang, Song Cao*
Organometallics, 2018, 37(3), 459–463
Cu-catalyzed tertiary alkylation of α-(trifluoromethyl)styrenes with tertiary alkylmagnesium reagents
Wenpeng Dai, Yingyin Lin,Yan Wan, Song Cao*
Org Chem Front, 2018, 5, 55–58
2017年
Bismuth(III)-promoted trifluoromethylthiolation of pyrazolin-5-ones with trifluoromethanesulfanamide
Qingyun Liu, Tao Huang, Xianghu Zhao, Jingjing Wu*, Song Cao*
ACS Omega, 2017, 2, 7755–7759 (Invited)
HMPA-Promoted Siladifluoromethylation of Di-, and Triarylmethanes with Ruppert−Prakash Reagent
Xinfei Ji, Xianghu Zhao, Hongyan Shi, Song Cao*
Chem - An Asian J, 2017, 12, 2794–2798
Direct copper-catalyzed oxidative trifluoromethylthiolation of aryl boronic acids with AgSCF3
Wei Wu, Biyun Wang, Xinfei Ji, Song Cao*
Org. Chem. Front., 2017, 4, 1299–1303
Cu-catalyzed stereoselective borylation of gem-difluoroalkenes with B2pin2
Juan Zhang, Wenpeng Dai, Qingyun Liu, Song Cao*
Org Lett, 2017, 19(12), 3283−3286
Synthesis of N,N-disubstituted 2-aminothiophenes by the cyclization of gem-difluoroalkenes with b-keto thioamides
Xuxue Zhang, Mingsheng Wu, Juan Zhang, Song Cao*
Org Biomol Chem, 2017, 15, 2436–2442
n-Butyllithium-mediated synthesis of N-aryl tertiary amines by reactions of fluoroarenes with secondary amines at room temperature
Yingyin Lin, Meng Li, Xinfei Ji, Jingjing Wu*,Song Cao*
Tetrahedron, 2017, 73, 1446–1472
Recent advances in the synthesis and C–F functionalization of gem-difluoroalkenes
Xuxue Zhang, Song Cao*
Tetrahedron Letters, 2017, 58, 375–392 (Invited)
2016年
LDA-mediated synthesis ofortho-cyanated diarylmethanes by reaction of fluoroarene with arylacetonitrile at room temperature
Fang Liang, Xinfei Ji, Juan Zhang, Song Cao*
Org. Chem. Front., 2016, 3, 1425−1429
Sterically controlled Cu-catalyzed or transition-metal-free cross-coupling of gem-difluoroalkenes with tertiary, secondary, and primary alkyl Grignard reagents
Wenpeng Dai, Hongyan Shi, Xianghu Zhao, Song Cao*
Org Lett, 2016, 18(17), 4284−4287
Mild and Copper-Free Stereoselective Cyanation of gem-Difluoroalkenes by Using Benzyl Nitrile as a Cyanating Reagent
Juan Zhang, Chengyuan Xu, Wei Wu, Song Cao*
Chem. Eur. J. 2016, 22, 9902–9908
Silver-Mediated anti-Markovnikov and Markovnikov-Selective Hydrotrifluoromethylthiolation of Terminal Alkynes
Wei Wu, Wenpeng Dai, Xinfei Ji, Song Cao*
Org Lett, 2016, 18(12), 2918–2921
Synthesis of Exocyclic Trisubstituted Alkenes via Nickel-Catalyzed Kumada Type Cross-Coupling Reaction of gem-Difluoroalkenes with di-Grignard Reagents
Wenpeng Dai, Xuxue Zhang, Juan Zhang, Yingyin Lin, Song Cao*
Adv Synth Catal, 2016, 358, 183–187
Synthesis of fluorovinyl pyrazolyl (thio)ethersby the reaction of gem-difluoroalkenes with pyrazolin-5-ones (thiones)
Tao Huang, Xianghu Zhao, Xinfei Ji, Wei Wu, Song Cao*
J Fluorine Chem, 2016, 182, 61–68
2015年
LDA-Mediated Synthesis of Triarylmethanes by Arylation of Diarylmethanes with Fluoroarenes at Room Temperature
Xinfei Ji, Tao Huang, Wei Wu, Fang Liang, Song Cao*
Org Lett, 2015, 17(20), 5069–5099
Mild and metal-free trifluoromethylation and pentafluoroethylation of gem-difluoroalkenes with TMSCF3 and TMSCF2CF3
Guanyi Jin, Xuxue Zhang, Dan Fu, Wenpeng Dai, Song Cao*
Tetrahedron, 2015, 71, 7892–7899
Metal-free one-pot sequential direct diarylation of pyrazolin-5-ones with diaryliodonium salts
Tao Huang, Xinfei Ji, Wei Wu, Fang Liang, Song Cao*
RSC Advances, 2015, 5, 66598–66601
Nickel-catalyzed Suzuki-Miyaura type cross-coupling reactions of (2,2-difluorovinyl)benzene derivatives with arylboronic acids
Yang Xiong, Tao Huang, Xinfei Ji, Jingjing Wu*, Song Cao*
Org Biomol Chem, 2015, 13, 7389–7392
Mild electrophilic trifluoromethylthiolation of ketones with trifluoromethanesulfanamide
Wei Wu, Xuxue Zhang, Fang Liang, Song Cao*
Org Biomol Chem, 2015, 13, 6992–6999
Copper-Catalyzed Coupling Cyclization of gem-Difluoroalkenes with Activated Methylene Carbonyl Compounds: Facile Domino Access to Polysubstituted Furans
Xuxue Zhang, Wenpeng Dai, Wei Wu, Song Cao*
Org Lett, 2015, 17(11), 2708–2711
Synthesis of monofluoroalkenes through selective hydrodefluorination of gem-difluoroalkenes with Red-Al®
Jingjing Wu,* Juan Xiao, Wenpeng Dai, Song Cao*
RSC Advances, 2015, 5, 34498–34501
Perfluorobutyliodide-assisted direct cyanomethylation of azoles and phenols with acetonitrile
Juan Zhang, Wei Wu, Xinfei Ji, Song Cao*
RSC Advances, 2015, 5, 20562–20565
Synthesis of fluorovinyl aryl ethers by a three component reaction of gem-difluoroalkenes with arylboronic acids and oxygen
Mingjin Wang, Fang Liang, Yang Xiong, Song Cao*
RSC Advances, 2015, 5, 11996–11999
Base-mediated direct fluoroalkenylation of 2-phenyl-1,3,4-oxadiazole, benzothiazole and benzoxazole with gem-difluoroalkenes
Xuxue Zhang, Yingyin Lin, Juan Zhang, Song Cao*
RSC Advances, 2015, 5, 7905–7908
2014年
Stereoselective synthesis of b-fluoroenyne by the reaction of gem-difluoroalkenes with terminal alkynes
Guanyi Jin, Juan Zhang, Wei Wu, Song Cao*
J Fluorine Chem, 2014, 168, 240–246
Synthesis of polyfluoroaryl-containing 1,2,3-triazoles by reaction of polyfluoroarenes, sodium azide and active methylene ketones/esters
Jingjing Wu,* Dan Fu, Song Cao*
J Fluorine Chem, 2014, 168, 230–235
Palladium- or Nickel-catalyzed Kumada Cross-coupling Reaction of gem-Difluoroalkenes and Monofluoroalkenes with Grignard Reagents
Wenpeng Dai, Juan Xiao, Guanyi Jin, Jingjing Wu *, Song Cao *
J Org Chem, 2014, 79,10537–10546
Copper-free Direct C–H Trifluoromethylation of Acetanilides with Sodium Trifluoromethanesulfinate
Mingxi Wu, Xinfei Ji, Wenpeng Dai, Song Cao*
J Org Chem, 2014, 79, 8984–8989
Synthesis of N-(a-Fluorovinyl)azoles by the Reaction of Difluoroalkenes with Azoles
Yang Xiong, Xuxue Zhang, Tao Huang, Song Cao*
J Org Chem, 2014, 79, 6395–6402, Featured article, Cover
Nickel-catalyzed N-heterocycle directed cross-coupling of fluorinated arenes with organozinc reagents
Senhan Xiao, Yang Xiong, Xuxue Zhang, Song Cao*
Tetrahedron, 2014, 70, 4405–4411
2013年
Copper-mediated trifluoromethylation of 5-iodotriazole with (trifluoromethyl)trimethylsilane promoted by silver carbonate
Dan Fu, Jian Zhang, Song Cao*
J Fluorine Chem, 2013, 156, 170–176
Copper(I)-catalyzed trifluoromethylation of phthalic anhydride derivatives with (trifluoromethyl)trimethylsilane
Mingxi Wu, Mingjin Wang, Song Cao*
Chin J Chem,2013, 31, 945-949 (Ranked as the second most accessed papers in Top 15 in July, 2013)
(Invited, Dedicated to the Special Fluorine Chemistry)
Transition-Metal-Free Sonogashira-Type Cross-Coupling of Alkynes with Fluoroarenes
Guanyi Jin, Xuxue Zhang, Song Cao*
Org Lett, 2013, 15 (12), 3114–3117
(This paper was highlighted in Synfacts, 2013, 9, 1115)
Non-catalytic pyridyl-directed alkylation and arylation carbon-fluorine bond of polyfluoroarenes with Grignard reagents
Yang Xiong, Jingjing Wu, Senhan Xiao, Juan Xiao, Song Cao*
J Org Chem, 2013, 78(9), 4599–4603
Novel Synthesis of 1,4,5-Trisubstituted 1,2,3-Triazoles via a One-pot Three-Component Reaction of Boronic acids, Azides and Active methylene ketones
Jian Zhang, Guanyi Jin, Senhan Xiao, Jingjing Wu, Song Cao*
Tetrahedron, 2013, 69, 2352–2356
NiCl2(PCy3)2-catalyzed hydrodefluorination of fluoroarenes with LiAl(O-t-Bu)3H
Juan Xiao, Jingjing Wu, Wenwen Zhao, Song Cao*
J Fluorine Chem, 2013, 146, 76–79
2012年
One-pot Three Component Synthesis of Polyfluoroarylated Arylacetates via VNSAr-SNAr Reaction
Yang Xiong, Jingjing Wu, Senhan Xiao, Song Cao*
Chin J Chem,2012, 30, 2747–2751
(Invited, Dedicated to the 60th Anniversary of East China University of Science and Technology)
One-Pot, Three-Component Synthesis of 1,4,5-Trisubstituted 1,2,3-Triazoles Starting from Primary Alcohols
Guanyi Jin, Jian Zhang, Dan Fu, Jingjing Wu, Song Cao*
Eur J Org Chem, 2012, 5446–5449
Synthesis of unsymmetrical biaryl ethers through nickel-promoted coupling of polyfluoroarenes with arylboronic acids and oxygen
Jian Zhang, Jingjing Wu, Yang Xiong, Song Cao*
Chem Commun, 2012, 48, 8553–8555
Oxidation of benzylic methylenes to ketones with Oxone-KBr in aqueous acetonitrile under transition metal free conditions
Lixia Yin, Jingjing Wu, Juan Xiao, Song Cao*
Tetrahedron Letters, 2012, 53, 4418–4421
Synthesis and Insecticidal Activities of Novel Analogues of Flubendiamide Containing a Hexafluoroisopropanol Moiety
Mingxi Wu, Wenwen Zhao, Guanyi Jin, Qingchun Huang, Song Cao*
Chin J Chem2012, 30, 1310–1314
(Invited, Dedicated to Professor Jun Zhou on the occasion of his 80th birthday)
Highly efficient NiCl2/NiCl2(PCy3)2 co-catalyzed hydrodefluorination of fluoroarenes and trifluorotoluenes with superhydride
Wenwen Zhao, Jingjing Wu, Song Cao*
Adv Synth Catal, 2012, 354(4), 574–578
Synthesis of Difluoromethyl-Containing α-Acyloxycarboxamide Derivatives through a Passerini Reaction and Desulfonylation
Jingjing Wu, Wenwen Zhao, Song Cao*
Eur J Org Chem, 2012, 1380–1387
2011年
Synthesis of novel gem-difluoromethylene-containing 1,2,3-triazoles via click reaction
Wenwen Zhao, Hui Li, Jian Zhang, Song Cao*
Chin J Chem2011,29, 2763–2768
(Invited, Dedicated to Professor Weiyuan Huang on the occasion of his 90th birthday)
Nickel-Catalyzed Hydrodefluorination of Fluoroarenes and Trifluorotoluenes with Superhydride (Lithium Triethylborohydride)
Jingjing Wu and Song Cao*
ChemCatChem, 2011, 3(10), 1582–1586
Novel synthesis of pseudopeptides bearing a difluoromethyl group by Ugi reaction and desulfanylation
Jingjing Wu, Hui Li, Song Cao*
Beilstein J Org Chem, 2011, 7, 1070–1074
(Invited, Thematic Series: Multicomponent Reaction)
ZnCl2-catalyzed hydrodefluorination of gem-difluoromethylene derivatives with lithium aluminum hydride
Jianhang Cheng, Jingjing Wu, Song Cao*
Tetrahedron Letters, 2011, 52, 3481–3484
Novel synthesis of difluoromethyl-containing 1,4-disubstituted 1,2,3-triazoles via a click-multicomponent reaction and desulfanylation strategy
Jian Zhang, Jingjing Wu, Li Shen, Guanyi Jin, Song Cao*
Adv Synth Catal, 2011, 353(4), 580–584
One-pot synthesis of difluoromethyl-containing dihydropyrimidinones catalyzed by Yb(PFO)3 under solvent and dehydrating agent free conditions
Mingxi Wu, Jinlong Yu, Wenwen Zhao, Jingjing Wu, Song Cao*
J Fluorine Chem, 2011, 132, 155–159
Non-catalytic conversion of C-F bonds of gem-difluoromethylene derivatives to C-H bonds with lithium aluminum hydride under room temperature
Jingjing Wu, Jianhang Cheng, Jian Zhang, Li Shen, Xuhong Qian, Song Cao*
Tetrahedron, 2011, 67, 285–288
2010年
K2CO3-assisted one-pot sequential synthesis of 2-trifluoromethyl-6-difluoromethylpyridine-3,5-dicarboxylates under solvent-free conditions
Li Shen, Song Cao*, Jingjing Wu, Hui Li, Jian Zhang, Mingxi Wu, Xuhong Qian*
Tetrahedron Letters, 2010, 51, 4866–4869
A mild and efficient synthesis of monofluorinated a-lactam pseudopeptides via a novel dehydrofluorination of Ugi products
Nianjin Liu, Song Cao*, Jingjing Wu, Li Shen, Jinlong Yu, Jian Zhang, Hui Li, Xuhong Qian*
Mol Divers, 2010, 14, 501–506
An efficient three-component domino synthesis of difluoromethyl-containing 1,4-dihydropyridines under solvent and catalyst free conditions
Hui Li, Jinlong Yu, Song Cao*, Li Shen, Mingxi Wu, Jianhang Cheng, Xuhong Qian*
Science China Chemistry, 2010, 53(7), 1509–1513
Antagonism of 4-substituted 1,4-dihydropyridine-3,5-dicarboxylates toward voltage-dependent L-type Ca2+ channels CaV1.3 and CaV1.2
Che-Chien Chang, Song Cao, Soosung Kang, Li Kai, Xinyong Tian, Prativa Pandey, Sara F. Dunne, Chi-Hao Luan, D. James Surmeier, Richard B. Silverman(第二作者)
Bioorg Med Chem, 2010, 18, 3147–3158
A General Strategy for Construction of Difluoromethyl Compound Library and its Application in Synthesis of Pseudopeptides bearing Terminal Difluoromethyl Group
Jingjing Wu, Song Cao*, Nianjin Liu, Li Shen, Jinlong Yu, Jian Zhang, Hui Li and Xuhong Qian
Org Biomol Chem, 2010, 8, 2386–2391
Synthesis and Insecticidal Activity of Heptafluoroisopropyl-Containing Benzoylphenylurea Structures
Jian Zhang, Xiuhong Tang, Isaac Ishaaya, Song Cao*, Jingjing Wu, Jinlong Yu, Hui Li, Xuhong Qian
J Agric Food Chem, 2010, 58(5), 2736–2740
2009年
Multicomponent Reactions Based on Fluoro-Containing Building Blocks
Jingjing Wu and Song Cao*
Curr Org Chem, 2009, 13(18), 1791–1840
(Invited, Guest Editor, Thematic Series: Multicomponent Reaction)
A revisit to the Hantzsch reaction: Unexpected products beyond 1,4-dihydropyridines
Li Shen,Song Cao*, Jingjing Wu, Jian Zhang, Hui Li, Nianjin Liu and Xuhong Qian*
Green Chemistry, 2009, 11, 1414–1420
New gem-difluoromethylene-containing isocyanide as a useful building block for the synthesis of difluorinated pseudopeptides via Ugi reaction
Nianjin Liu, Song Cao* Li Shen, Jingjing Wu, Jinlong Yu, Jian Zhang, Hui Li, Xuhong Qian*
Tetrahedron Letters, 2009, 50, 1982–1985
2008年
One-Pot Synthesis of Trifluoromethyl-Containing Pyrazoles via Sequential Yb(PFO)3- Catalyzed Three-Component Reaction and IBX-Mediated Oxidation
Li Shen, Jian Zhang, Song Cao*, Jinlong Yu, Nianjin Liu, Jingjing Wu, Xuhong Qian*
Synlett 2008, 19, 3058–3062
Ytterbium (III) Perfluorooctanoate-catalyzed One-pot Three-component Synthesis of Fully Substituted Pyrazoles under Solvent-free Conditions
Li Shen, Song Cao*, Nianjin Liu, Jingjing Wu, Xin Feng, Xuhong Qian*
Synlett 2008, 9, 1341–1344
One-Pot Three Component Synthesis of Heteroaryled arylacetates via VNSAr-SN Reaction using N-Methylpyrrolidone as General Solvent
Song Cao*, Jingjing Wu, Lina Li, Longjie Zhu, Jian Zhang, Jinlong Yu, Xuhong Qian
Org Biomol Chem, 2008, 6 (7), 1293–1297
Solvent-Free Ugi Four-Component Condensation: Application to Synthesis of Philanthotoxins-12 Analogues
Nianjin Liu, Song Cao*, Jingjing Wu, Jinlong Yu, Li Shen, Xin Feng and Xuhong Qian*
Tetrahedron, 2008, 64(18), 3877–4142
Synthesis of Thiohydantoins under One-Pot Three-Component Solvent-Free Conditions
Song Cao*, Longjie Zhu, Chuanmeng Zhao, Xiuhong Tang, Huajun Sun, Xin Feng, Xuhong Qian
Monatshefte fur Chemie, 2008, 139, 923-926
2007-2001年
An Efficient and Practical Method for the Synthesis of 1-(2,6-Difluorobenzoyl)-3-[2’-alkyl-3’-oxopyridazin-4’- yl]ureas as Potential Chitin Synthesis Inhibitors
Song Cao*, Deli Lu, Chuanmeng Zhao, LinaLi, Qingchun Huang, Xuhong Qian*
Monatshefte fur Chemie, 2006, 137(6), 779–784
Syntheses, Antifeedants and QSAR Analysis of New Oxa(thia)diazolyl 3(2H)-Pyridazinones
Song Cao*, Na Wei, Chuanmeng Zhao, Lina Li, Qingchun Huang, Xuhong Qian*
J of Agric and Food Chem, 2005, 53, 3120–3125
Synthesis and Antifeedant Activity of New Oxadiazolyl 3(2H)-Pyridazinones
Song Cao, Xuhong Qian*, Gonghua Song, Bing Chai, Zhisheng Jiang
J of Agric and Food Chem, 2003, 51, 152–155
Synthesis of 3-Aryl-1,3,5-pentanetricarboxylic acid trialkyl esters via a Tandem Addition- Rearrangement-Addition Reaction
Song Cao*, Zheng Zhang, Ailong Fan,Ziming Huang
Monatshefte fur Chemie, 2003, 134, 529–532
Syntheses and insecticidal activity of new 2-(5-(trifluoromethyl)pyridyloxymethyl)-1,3,4– oxadiazoles
Song Cao, Xuhong Qian*, Gonghua Song, Qingchun Hung
J of Fluorine Chem, 2002, 117, 63–66
N’-tert-butyl-N’-aroyl-N-(alkoxycarbonylmethyl)-N-aroylhydrazines, A Novel Nonsteroidal Ecdysone Agonist: Syntheses , Conformational and Crystal Structure Analysis
Song Cao, Xuhong Qian*, Gonghua Song
Canadian J of Chem, 2001, 79, 272–278
A Novel and Practical Amination of 4,5-Dichloropyridazinones via Hydrazine Hydrate Reduction
Song Cao, Xuhong Qian*, Gonghua Song, Xiayu Huang
Chemistry Letters, 2001, 1, 54–55
专利：
含七氟异丙基苯甲酰脲类化合物及其用途
曹松,钱旭红, 唐秀红, 黄青春, 孙华君, 张建
发明专利申请号：2008 1003 4794.8，申请日：2008年3月18日
公开号：CN 1015 38227 A，公开日：2009年9月23日
授权专利号：ZL 2008 1 0034794.8，授权公告日：2012年6月6日
Benzoylurea compounds bearing heptafluoroisopropyl and uses thereof
Song Cao, Xuhong Qian, Xiuhong Tang, Jian Zhang, QingChun Huang, Huajun Sun
国际申请号：PCT/CN2009/070858，国际申请日：2009年3月18日
国际公布号：WO/2009/115040 A1，国际公布日：2009年9月24日
含2’-羟基六氟异丙基的邻苯二甲酰胺类化合物及其用途
曹松, 吴明熹, 黄青春, 尹黎霞, 吴晶晶
发明专利申请号：2011 1019 1776.2，申请日：2011年07月11日
公布号：CN 1023 20998 A，公布日：2012年1月18日
授权专利号：ZL 2011 1 0191776.2，授权公告日：2014年8月20日
含二氟(亚)甲基邻甲酰胺基苯甲酰胺类化合物
曹松, 吴晶晶, 尹黎霞, 黄青春, 张建
发明专利申请号：2012 1006 0581.9A，申请日：2012年03月08日
公布号：CN 1026 17551 A，公布日：2012年8月01日
2’-氯六氟异丙基苯甲酰脲类化合物及其用途
曹松, 程建航, 熊扬, 金观毅, 肖娟
发明专利申请号：2012 10148195.5，申请日：2012年05月15日
公开号：CN 102702031 A，公开日：2012年10月03日
制备-三氟甲基4-取代苯胺类化合物的方法
曹松, 吴明熹, 纪鑫飞, 张娟, 代文朋
申请号：2014 10275913.4，申请日：2014年06月19日
公布号：CN 104072324 A，公布日：2014年10月01日
授权专利号：ZL 2014 1 0275913.4，授权公告日：2016年6月8日
含氟和氮杂环的烯烃类化合物及其制备方法和用途
曹松, 熊扬, 黄涛, 吴伟, 金观毅
申请号：2014 10134330.X，申请日：2014年04月04日
公布号：CN 104292165 A，公布日：2015年01月21日
授权专利号：ZL 2014 1 0134330.X，授权公告日：2017年1月4日
由含氟烯烃制备多取代烯烃类化合物的方法
曹松, 代文朋, 肖娟, 吴晶晶, 林赢银
申请号：2014 10831434.6，申请日：2014年12月23日
公布号：CN 104478640 A，公布日：2015年04月01日
由偕二氟烯烃制备多取代呋喃类化合物的方法
曹松, 张旭雪, 代文朋, 林赢银, 吴伟
申请号：2015 10202778.5，申请日：2015年04月24日
公布号：CN 104910105 A，公布日：2015年09月16日
授权专利号：ZL 2015 1 0202778.5，授权公告日：2017年4月5日
制备a-三氟甲硫基化羰基类化合物的新方法
曹松, 吴伟, 张旭雪, 梁芳, 王惠
申请号：2015 10329114.5，申请日：2015年06月16日
公布号：CN 104974065 A，公布日：2015年10月14日
Oral presentation 和 Poster presentation
Borylation and Cyanation of gem-Difluoroalkenes Reactions
第十届全国有机化学学术会议
2017年12月19–21日；深圳，南方科技大学；Poster。
E-式含单氟乙烯基吡啶基醚的合成
第十四届全国氟化学会议
2016年11月18–20日；福州大学；Poster。
New reactions for the functionalization of C–F bond of gem-difluoroalkenes
21th International Symposium on Fluorine Chemistry
2015年8月23–28日；意大利，米兰理工大学(科莫湖校区)；口头报告及Poster
苯胺类化合物的三氟甲基化及含氟农药的创制
2015年氟化工技术交流暨产品推广会(第三届中国阜新氟化工产业高峰论坛及氟产品展销会)
2015年5月28–30日；辽宁，阜新；邀请报告
Some new reactions for the functionalization of C–F bond
5rd China-Japan-Korea Joint Seminar on Fluorine Chemistry
2014年10月19–21日；中国科学院上海有机化学研究所；邀请报告
Synthesis of N-(a-Fluorovinyl)azoles by the Reaction of Difluoroalkenes with Azoles
“末端炔与偕二烯氟反应高选择性地合成β-氟代烯炔”
第十三届全国氟化学会议
2014年8月20–23日；上海应用技术学院；口头报告及Poster。
A Practical Approach for the Stereoselective Synthesis of N-(a-Fluorovinyl)azoles by the Reaction of gem-Difluoroalkenes with Azoles
4th International Symposium on Organofluorine Compounds (Bordeaux Fluorine Days)
2014年7月6–10日；法国，波尔多，Poster
镍催化的多氟芳烃、苯硼酸、氧气三组分反应合成不对称二苯醚
第十二届全国氟化学会议
2012年10月12–16日；南昌，江西师范大学；邀请口头报告
A general strategy for construction of a difluoromethyl (CF2H) compound library and its application in Ugi, Passerini, and Click reactions
20th International Symposium on Fluorine Chemistry
2012年7月23–27日；日本，京都大学；口头报告
NiCl2/NiCl2(PCy3)2共同催化氢化多氟和三氟甲基芳烃”
中国化学会第七届有机化学学术会议
2011年11月12–15日；江苏省，南京大学；口头报告
Hydrodefluorination of different carbon-fluorine bonds with or without metal catalysts
The International Workshop on Organofluorine Chemistry
2011年10月28–30日；中国，天津大学；邀请报告
含2'-羟基六氟异丙基的氟虫双酰胺类似物的合成及杀虫活性
第二届全国高校中青年学者与企业家论坛
2011年7月28–30日；山东省，泰安市；邀请报告
The synthesis of three types of pseudopeptides bearing CF2H via multicomponent reactions
Twelfth Tetrahedron Symposium
2011年6月21–24日；西班牙，锡切斯；Poster
基于含氟砌块的多组分反应构建结构多样的含二氟甲基小分子
第十一届全国氟化学会议
2010年10月13–15日；中国，上海大学；邀请报告
Non-catalytic Conversion of C-F Bonds of gem-Difluoromethylene Derivatives to C-H Bonds with Lithium Aluminum Hydride under Room Temperature
3rd Korea-Japan-China Joint Seminar on Fluorine Chemistry
2010年9月4–8日；韩国，大田；邀请报告
Synthesis and insecticidal activity of benzoylphenylureas with several fluorine-containing fragments
12th IUPAC International Congress of Pesticide Chemistry
2010年7月4–8日；澳大利亚，墨尔本；Poster
A novel three-component synthesis of difluoromethyl-containing dihydropyrimidinones under solvent and dehydrating agent free conditions
2010 Eleventh Tetrahedron Symposium Beijing
2010年6月23–25日；中国，北京大学；Poster
含氟芳香精细化学品的关键技术、产业化及应用前景
2009年国际氟硅精细化工产业发展高峰论坛
2009年7月28–31日；中国，福建，邵武；特邀报告
含氟农药及其中间体
第九届国际精细化工市场研讨会
2009年11月26–27日；中国，杭州；邀请报告
New difluorinated isocyanide and its application in Ugi reaction
19th International Symposium on Fluorine Chemistry
2009年8月23–28日；美国，Jackson Hole；口头报告
New Strategy for the Synthesis of Fluorinated Compounds: Multicomponent Reactions including Fluoro-containing Building Blocks (MCRs-FBB)
The 4th International Conference on MultiComponent Reactions and Related Chemistry
2009年5月24–28日；俄罗斯，叶卡捷琳堡，Ural State Technical University；口头报告
全氟辛酸镱催化的三组分反应合成含三氟甲基全取代吡唑 ----- 兼谈以含氟砌块多组分反应构建含氟化合物库战略
第十届全国氟化学会议；
2008年10月11–14日；中国，武汉，华中科技大学；口头报告
